You always need to look at your subject and how it interacts with each object in its environment. Sunset does provide a small moment in time for you to see that shot and take advantage before you have to wait another 24 hours.
This shot was taken during sunset at San Carlos Borroméo de Carmelo Mission.
Image Stats: [Canon 5D MII]
| Aperture: f/29 | Shutter: 1/6400 | ISO: 100 | Focal: 270mm |